Citation:
Lev D. Gelb, Malgorzata Sliwinska-Bartkowiak and Keith E. Gubbins, Fundamentals of Adsorption 6 (1999) 497-502

Abstract: We present results from experiments and simulations for the effects of confinement on liquid-liquid phase equilibria. Experimental phase diagrams for the nitrobenzene/\mbox{$n$-hexane} mixture in controlled pore glasses are obtained by nonlinear dielectric effect and light transmission measurements. We also use computer simulations of a Lennard-Jones mixture in several cylindrical pores to study the short-time dynamics of phase separation upon temperature quenching.

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