| Publications while at WashU: 30. Khusnutdinova, J. R.; Luo, J.; Rath, N. P.; Mirica, L. M.* “Late First Row Transition Metal Complexes of a Tetradentate Pyridinophane Ligand: Electronic Properties and Reactivity Implications”, Inorg. Chem., 2013, 52, 3920-3932, Pdf 29. Cascella, B.; Mirica, L. M.* “Kinetic Analysis of Iron-Dependent Histone Demethylases: a-Ketoglutarate Substrate Inhibition and Potential Relevance to the Regulation of Histone Demethylation in Cancer Cells”, Biochemistry, 2012, 51, 8699-8701, Pdf 28. Tang, F.; Qu, F.; Khusnutdinova, J. R.; Rath, N. P.; Mirica, L. M.* “Structural and Reactivity Comparison of Analogous Organometallic Pd(III) and Pd(IV) Complexes”, Dalton Trans., 2012, 41, 14046-14050. Pdf 27. Tang, F.; Zhang, Y.; Rath, N. P.; Mirica, L. M.* “Detection of Pd(III) and Pd(IV) Intermediates during the Aerobic Oxidative C-C Bond Formation from a Pd(II) Dimethyl Complex”, Organometallics, 2012, 31, 6690-6696. Pdf 26. Khusnutdinova, J. R.; Mirica, L. M.* “Organometallic Pd(III) Complexes in C-C and C-Heteroatom Bond Formation Reactions”, invited book chapter in C-H Activation and Functionalization, Transition Metal Mediation, Royal Society of Chemistry, 2012, in press. 25. Khusnutdinova, J. K.; Qu, F.; Zhang., Y.; Rath, N. P.; Mirica, L. M.* “Formation of the Pd(IV) Complex [(Me3tacn)PdIVMe3]+ through Aerobic Oxidation of (Me3tacn)PdIIMe2 (Me3tacn = N,N’,N’’-trimethyl-1,4,7-triazacyclononane)”, Organometallics, 2012, 4627-4630. Pdf 24. Mirica L. M.;* Khusnutdinova, J. R. “Structure and Electronic Properties of Pd(III) Complexes” Coord. Chem. Rev. 2012, 257, 299-314. Pdf 23. Evangelio, E.; Rath, N. P.; Mirica L. M.* “Cycloaddition reactivity studies of first-row transition metal–azide complexes and alkynes: an inorganic click reaction for metalloenzyme inhibitor synthesis” Dalton Trans. 2012, 8010-8021. Invited contribution for the “New Talent Americas” issue. Pdf 22. Sharma. A. K.; Pavlova, S. T.; Kim, J.; Finkelstein, D.; Hawco, N. J.; Rath, N. P.; Kim, J.; Mirica L. M.* “Bifunctional Compounds for Controlling Metal-Mediated Aggregation of the Aβ42 Peptide” J. Am. Chem. Soc., 2012, 134, 6625-6636. Pdf 21. Khusnutdinova, J. K.; Rath, N. P.; Mirica L. M.* “The Aerobic Oxidation of a Pd(II) Dimethyl Complex Leads to Selective Ethane Elimination from a Pd(III) Intermediate” J. Am. Chem. Soc., 2012, 134, 2414-2422. Pdf 20. Luo, J., Khusnutdinova J. R., Rath N., Mirica L. M.* “Unsupported d8-d8 Interactions in Cationic PdII and PtII Complexes: Evidence for a Significant Metal-Metal Bonding Character” Chem. Comm., 2012, 48, 1532-1534. Invited contribution for the “Emerging Investigators” issue. Pdf. 19. Luo, J.; Rath, N. P.; Mirica L. M.* “Dinuclear Co(II)Co(III) Mixed-Valence and Co(III)Co(III) Complexes with N- and O-Donor Ligands: Characterization and Water Oxidation Studies” Inorg. Chem., 2011, 50, 6152-6157. Pdf 18. Khusnutdinova, J. K.; Rath, N. P.; Mirica L. M.* “Dinuclear Palladium(III) Complexes with a Single Unsupported Bridging Halide Ligand: Reversible Formation from Mononuclear Palladium(II) or Palladium(IV) Precursors” Angew. Chem. Int. Ed. 2011, 50, 5532-5536. Pdf 17. Khusnutdinova, J. K.; Rath, N. P.; Mirica L. M.* “Stable Mononuclear Pd(III) Complexes and Their C-C Bond Formation Reactivity ” J. Am. Chem. Soc., 2010, 132, 7303-7305. Pdf Featured as "News Of The Week" in Chem. & Eng. News, May 24, 2010, page 9. Publications from postdoctoral and PhD work: 16. Verma P., Weir J., Mirica L. M., Stack T. D. P.* “Tale of a Twist: Magnetic and Optical Switching in Copper(II) Semiquinone Complexes” Inorg. Chem., 2011, 50, 9816-9825. Pdf 15. Op’t Holt B. T.; Vance M. A.; Mirica L. M.; Heppner D. E.; Stack T. D. P.;* Solomon E. I.* “Reaction Coordinate of a Functional Model of Tyrosinase: Spectroscopic and Computational Characterization” J. Am. Chem. Soc., 2009, 131, 6421-6438. Pdf 14. Humphreys, K. J.; Mirica, L. M.; Wang Y.; Klinman, J. P.* “Galactose Oxidase as a Model for Reactivity at a Copper Superoxide Center.” J. Am. Chem. Soc., 2009, 131, 4657-4663. Pdf 13. Mirica, L. M.; McCusker, K. P.; Munos, J. W.; Liu, H. W.; Klinman, J. P.* “18O Kinetic Isotope Effects in Non-Heme Iron Enzymes: Probing the Nature of Fe/O2 Intermediates.”J. Am. Chem. Soc., 2008, 130, 8122-8123. Pdf 12. Mirica, L. M.; Klinman, J. P.* “The Nature of O2 Activation by the Ethylene-Forming Enzyme ACC Oxidase.” Proc. Natl. Acad. Sci. U. S. A., 2008, 105, 1814-1819. Pdf 11. Welford, R. W. D.; Lam, A.; Mirica, L. M.; Klinman, J. P.* “Partial Conversion of Hansenula polymorpha Amine Oxidase into a ‘Plant’ Amine Oxidase: Implications for Copper Chemistry and Mechanism.” Biochemistry, 2007, 46, 10817-10827. Pdf 10. Thrower, J. T.; Mirica, L. M.; McCusker, K. P.; Klinman, J. P.* “Mechanistic Investigations of 1-Aminocylcyclopropane 1-Carboxylic Acid Oxidase with Alternate Cyclic and Acyclic Substrates.” Biochemistry, 2006, 45, 13108-13117. Pdf 9. Mirica, L. M.; Rudd, D. J.; Vance, M.; Solomon, E. I.;* Hedman, B.;* Hodgson, K. O.;* Stack, T. D. P.* “A m-h2:h2-Peroxodicopper(II) Complex with a Secondary Diamine Ligand: A Functional Model of Tyrosinase.” J. Am. Chem. Soc., 2006, 128, 2654-2665. Pdf 8. Cole, A. P.; Mahadevan, V.; Mirica, L. M.; Ottenwaelder, X.; Stack, T. D. P.* “Bis(m-oxo)dicopper(III) Complexes of a Homologous Series of Simple Peralkylated 1,2-Diamines: Steric Modulation of Structure, Stability, and Reactivity.” Inorg. Chem., 2005, 44, 7345-7364. Pdf 7. Yoon, J.; Mirica, L. M.; Stack, T. D. P.;* Solomon, E. I.* “Variable-Temperature Variable-Field Magnetic Circular Dichroism Studies of Tris-Hydroxy and m3-Oxo Bridged Trinuclear Cu(II) Complexes: Geometric and Electronic Structures of the Native Intermediate of Multicopper Oxidases.” J. Am. Chem. Soc., 2005, 127, 13680-13693. Pdf 6. Mirica, L. M.; Vance, M.; Rudd, D. J.; Hedman, B.;* Hodgson, K. O.;* Solomon, E. I.;* Stack, T. D. P.* “Tyrosinase Reactivity in a Model Complex: An Alternative Hydroxylation Mechanism.” Science, 2005, 308, 1890-1892. Featured as a perspective in Science, 2005, 308, 1876-1877 and a science concentrate in Chem. & Eng. News, 2005, 83, 26, 38. Pdf 5. Mirica, L. M.; Stack, T. D. P.* “A Tris(m-hydroxy)tricopper(II) Complex as a Model of the Native Intermediate in Laccase and Its Relationship to a Binuclear Analogue.” Inorg. Chem., 2005, 44, 2131-2133. Pdf 4. Pratt, R. C.; Mirica, L. M.; Stack, T. D. P.* “Snapshots of a Metamorphosing Cu(II) Ground State in a Galactose Oxidase-Inspired Complex.” Inorg. Chem., 2004, 43, 8030-8039. Pdf 3. Yoon, J.; Mirica, L. M.; Stack, T. D. P.;* Solomon, E. I.* “Spectroscopic Demonstration of a Large Antisymmetric Exchange Contribution to the Spin-Frustrated Ground State of a D3 Symmetric Hydroxy-Bridged Trinuclear Cu(II) Complex: Ground-to-Excited State Superexchange Pathways.” J. Am. Chem. Soc., 2004, 126, 12586-12595. Pdf 2. Mirica, L. M.; Ottenwaelder, X.; Stack, T. D. P.* “Structure and Spectroscopy of Copper–Dioxygen Complexes.” Chem. Rev., 2004, 104, 1013-1046. Pdf 1. Mirica, L. M.; Vance, M.; Rudd, D. J.; Hedman, B.;* Hodgson, K. O.;* Solomon, E. I.;* Stack, T. D. P.* “A Stabilized m-h2:h2-Peroxodicopper(II) Complex with a Secondary Diamine Ligand and Its Tyrosinase-like Reactivity.” J. Am. Chem. Soc. 2002, 124, 9332-9333. Pdf |